Search results for "Molar refractivity"

showing 2 items of 2 documents

Dielectric polarization and polarizability of 1-pentanol+n-octane mixtures from static dielectric constant and refractive index data at 0,25 and 45�C

1990

Static dielectric constants and refractive indices of 1-pentanol+n-octane mixtures were measured in the temperature range between 0 and 45°C. Data discussed in terms of Kirkwood correlation factor and Lorentz-Lorenz molar refractivity give information on the short range intermolecular interactions between the components. The role played by the nonpolar n-octane in the destruction of 1-pentanol oligomers is also pointed out.

Bond dipole momentChemistryIntermolecular forceBiophysicsThermodynamicsDielectricAtmospheric temperature rangeBiochemistryPolarization densityComputational chemistryMolar refractivityPolarizabilityPhysical and Theoretical ChemistryMolecular BiologyRefractive indexJournal of Solution Chemistry
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A novel approach to determining physicochemical and absorption properties of 6-fluoroquinolone derivatives: experimental assessment

2002

The ToSS MoDe approach is used to estimate the n-octanol/buffer partition coefficient, the apparent intestinal absorption rate constant and intestinal permeability from a 6-fluoroquinolone data set. Improved in silico methods for predicting a drug's ability to be transported across biological membranes and other biopharmaceutical properties is highly desirable to optimize new drug development. The physicochemical property (Log P) of 26 6-fluoroquinolone derivatives and the absorption properties (Log K(a) and Log P(eff)) of 21 derivatives were well described by the present approach. The models obtained confirm the important role of lipophilicity in the absorption process and its relation wit…

MaleAbsorption (pharmacology)ChemistryAnalytical chemistryPharmaceutical ScienceThermodynamicsGeneral MedicineModels BiologicalIntestinal absorptionRatsPartition coefficientMoment (mathematics)Structure-Activity RelationshipSarafloxacinAnti-Infective AgentsIntestinal AbsorptionMolar refractivityLipophilicityAnimalsRats WistarFluoroquinolonesBiotechnologyAntibacterial agentEuropean Journal of Pharmaceutics and Biopharmaceutics
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